ETHYL ACETOACETATE FOR SYNTHESIS

Code: 8096220100 D2-231

Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)Density (d 20 °C/ 4 °C): 1.028 - 1.030Identity (IR): passes test

Application

Ethyl...


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€24.80 EACH
€30.50 inc. VAT

Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)Density (d 20 °C/ 4 °C): 1.028 - 1.030Identity (IR): passes test

Application

Ethyl acetoacetate can be used as a reactant to synthesize: 7-hydroxycoumarin derivatives via Pechmann condensation reaction with 1,3-dihydroxybenzene in the presence of acid catalysts.2,6-disubstituted piperidine alkaloid, (−)-pinidinone via stereoselective α-aminoallylation followed by Grubbs′ olefin cross-metathesis reaction. Michael addition products via Michael addition reaction with chalcones and azachalcones in the presence of a base catalyst.α, β-unsaturated carbonyl compounds via Knoevenagel condensation reaction with glyceraldehyde acetonide in the presence of a base catalyst. It can be also utilized as a reactant in the transesterification and asymmetric hydrogenation reactions to produce valuable products.

Packaging

1, 2.5 l in Plastic bottle

25 l in Plastic container

assay≥98.0% (GC)
autoignition temp.350 °C
density1.03 g/cm3 at 20 °C
expl. lim.1.0-54 % (v/v)
formliquid
InChI keyXYIBRDXRRQCHLP-UHFFFAOYSA-N
InChI1S/C6H10O3/c1-3-9-6(8)4-5(2)7/h3-4H2,1-2H3
mp-53.3 °C
pH4.0 (20 °C, 110 g/L in H2O)
potency3980 mg/kg LD50, oral (Rat), >5000 mg/kg LD50, skin (Rabbit)
Quality Level200
solubility130.3 g/L
storage temp.2-30°C
transition tempflash point 73.5 °C
vapor pressure0.26 hPa ( 20 °C)
Cas Number141-97-9
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